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Steve Paskey
04-12-2006, 09:52 AM
Move over, Gougeon brothers ...
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New Glue Derived from Clinging Mussels
By Michael Schirber
LiveScience Staff Writer
posted: 13 April 2005

Scientists have derived a new glue from a natural adhesive made by rock-clinging mollusks. It could provide an environmentally friendly alternative to current wood-binding materials.

Kaichang Li from Oregon State University became interested in the idea during a trip to the beach.

"I was amazed at the ability of these small mollusks to attach themselves so strongly to rocks," Li said. "Thinking about it, I didn't know of any other type of adhesive that could work this well in water and withstand so much force."

Mussels endure battering waves and can hitch rides on the hulls of ships, becoming an invasive threat to local ecologies.

This is not the first time researchers have been attracted to the sticky power of mussels. But Li has made a real and potentially commercial glue from his research. The secret to the mussels’ staying power is tiny threads, called byssus. These tentacles, which can reach more than two inches in length, are made of a protein with a high level of stuff called phenolic hydroxyls.

"It is very difficult to get mussels to produce a lot of this protein," Li told LiveScience. "But I am a bio-chemist and I know that protein is protein."

Li's research group was able to mimic the mussel’s unique protein by adding molecules with phenolic hydroxyl groups to soybean flour – an abundant and inexpensive source of protein. The derivative is renewable and may reduce the need for urea-formaldehyde wood adhesives, which are associated with health concerns and are based on expensive petroleum.

Possible applications for the mussel-inspired glue are wood composite products like plywood, oriented strand board, particle board, and laminated veneer lumber products. Li’s group has three patents pending.

"The plywood we make with this adhesive can be boiled for several hours and the adhesive holds as strong as ever," Li said. "Regular plywood bonded with urea-formaldehyde resins could never do that."

Interestingly, there is a long history of spinning the mussels’ byssus into fine threads for making cloth. The fabled Golden Fleece from the story of Jason and the Argonauts is believed to have been woven from byssus.

Nicholas Carey
04-12-2006, 01:19 PM
I posted this a few months back, from a piece on the Journal of Light Construction (http://www.jlconline.com/) (trade rag for house carpenters, but pretty useful reading and some good stuff if your interesting in that sort of thing).

According to the JLC article, as I remember it, the technology had already been licensed to manufacturers. If you go to the JLC web site (see above) and search for "mussels", the article will show up. Here's the bit regarding commercial usage:

Li admits that the boiling test is somewhat extreme; it's voluntary even for exterior grade plywood and OSB. In those exterior products, urea formaldehyde doesn't provide the needed weather resistance, which is why CDX plywood and OSB use the more stable (and more expensive) phenolic adhesive.

Li has already struck deals with chemical company Hercules to manufacture commercial versions of his new adhesive. And in May, Columbia Forest Products announced plans to convert all its hardwood plywood mills to the soy-based glue. Says Columbia spokesman John McIsaac, "The new adhesive outperforms our existing urea formaldehyde adhesive for both water resistance and strength. So why wouldn't we jump on it?" He adds, "With this product, we have no emissions at all, and that's better for our employees and for our customers."

But what about exterior panels? Says Li, "We are working with Louisiana-Pacific to get that going, and we did successfully make some OSB. They cut a corner off a panel and threw it in boiling water while we were working there, and boiled it for something like two days, and it held together. It was pretty amazing."

Currently, Li notes, modern OSB plants have to deal with excess formaldehyde. To control emissions, he says, "they actually use natural gas and burn everything up. But the problem is that the natural-gas bill is larger than their profit. That's lots of money."

A natural glue that can achieve better adhesion and durability with less toxic risk has the potential to spread throughout the industry. Modified soy protein chemistry also has possible uses in site-applied glue and for better-adhering paints and coatings. "We're working on that," Li says. "But we aren't there yet."

Peter Malcolm Jardine
04-14-2006, 10:24 PM
Wow, that's incredibly cool.

Tom Lathrop
04-16-2006, 11:04 AM
I believe there was work done on this more than 40 years ago for the dental industry. I wonder how this is different or is it more economical. The glue dentists use for gluing caps and crowns is fantastic. Any dentists or anyone else know anything about that.